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Unnamed (Monoclinic Polymorph of Calcium Carbonate)

Valid as an unnamed mineral
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Formula:
CaCO3
Specific Gravity:
2.76
Crystal System:
Monoclinic
Polymorph of:
The original paper/mention is discussed: "The origin seems to have been strictly organic, thus disqualifying the compound as a mineral". This seems strange as the material seems to be of a natural origin.

Crystallographical data is in a good agreement with corresponding synthetic analogue that is known to form at high pressure (15 kbar) and room temperature.

From a coral, in a deep-water environment with a relatively high hydrostatic pressure.

Chemical data wt.%, analysis approximated as it is artificially normalized to 100%:

Na2O 0.55
K2O 0.10
CaO 47.20
MgO 6.26
SrO 0.37
V2O5 0.04
Fe2O3 0.04
Al2O3 0.11
P2O5 0.05
SiO2 0.14
CO2 44.14

This corresponds to (Ca0.84Mg0.16)CO3.


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Unique IdentifiersHide

Mindat ID:
55015
Long-form identifier:
mindat:1:1:55015:8

IMA Classification of Unnamed (Monoclinic Polymorph of Calcium Carbonate)Hide

IMA status notes:
Unnamed (probably valid)

Physical Properties of Unnamed (Monoclinic Polymorph of Calcium Carbonate)Hide

Density:
2.76 g/cm3 (Measured)    2.82 g/cm3 (Calculated)

Chemistry of Unnamed (Monoclinic Polymorph of Calcium Carbonate)Hide

Mindat Formula:
CaCO3
Element Weights:
Element% weight
O47.957 %
Ca40.043 %
C12.000 %

Calculated from ideal end-member formula.
O
Ca
C

Crystallography of Unnamed (Monoclinic Polymorph of Calcium Carbonate)Hide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 6.290(2) Å, b = 4.934(2) Å, c = 7.979(3) Å
β = 107.571(2)°
Ratio:
a:b:c = 1.275 : 1 : 1.617
Unit Cell V:
236.07 ų (Calculated from Unit Cell)
Z:
4
Comment:
from a Rietveld refinement

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.994 Å(100)
2.4655 Å(15)
1.8861 Å(25)
1.8514 Å(15)

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Unnamed (Monoclinic Polymorph of Calcium Carbonate)Hide

References for Unnamed (Monoclinic Polymorph of Calcium Carbonate)Hide

Localities for Unnamed (Monoclinic Polymorph of Calcium Carbonate)Hide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
South China Sea
 
 
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