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Voglite

A valid IMA mineral species - grandfathered
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About VogliteHide

Formula:
Ca2Cu(UO2)(CO3)4 · 6H2O
Colour:
Bright grass-green, emerald-green
Lustre:
Pearly
Specific Gravity:
2.8
Crystal System:
Monoclinic
Name:
Named after Josef Florian Vogl (November 6, 1818 Kamenický Šenov - October 1, 1896 in Horní Blatná), Austrian mining official.
A secondary mineral formed from the alteration of Uraninite.

Easily confused with liebigite (Axelrod et al. 1951).


Unique IdentifiersHide

Mindat ID:
4199
Long-form identifier:
mindat:1:1:4199:3

Similar NamesHide

VoggiteA valid IMA mineral speciesNa2Zr(PO4)(CO3)(OH) · 2H2O
VogtiteA synonym of Ferrobustamite

IMA Classification of VogliteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca2Cu2+(U6+O2)(CO3)4·6H2O
First published:
1853

Classification of VogliteHide

5.EE.05

5 : CARBONATES (NITRATES)
E : Uranyl Carbonates
E : UO2:CO3= 1:4
15.3.5.1

15 : HYDRATED NORMAL CARBONATES
3 : AmBn(XO3)p·xH2O, with (m+n):p = 1:1
11.11.11

11 : Carbonates
11 : Carbonates of Cr and U

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
VglIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of VogliteHide

Pearly
Colour:
Bright grass-green, emerald-green
Streak:
Light green
Tenacity:
Brittle
Cleavage:
Perfect
{010}
Density:
2.8 g/cm3 (Measured)    3.06 g/cm3 (Calculated)

Optical Data of VogliteHide

Type:
Biaxial (+)
RI values:
nα = 1.541 nβ = 1.547 nγ = 1.564
2V:
Measured: 60° , Calculated: 62°
Max. Birefringence:
δ = 0.023
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Low (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v strong
Pleochroism:
Visible
Comments:
X = Deep bluish green
Y = Deep bluish green
Z = Pale yellowish

Chemistry of VogliteHide

Mindat Formula:
Ca2Cu(UO2)(CO3)4 · 6H2O
Element Weights:
Element% weight
O42.001 %
U31.243 %
Ca10.521 %
Cu8.341 %
C6.306 %
H1.588 %

Calculated from ideal end-member formula.
O
U
Ca
Cu
C
H

Crystallography of VogliteHide

Crystal System:
Monoclinic
Cell Parameters:
a = 25.97 Å, b = 24.5 Å, c = 10.7 Å
β = 104°
Ratio:
a:b:c = 1.06 : 1 : 0.437
Unit Cell V:
6,605.81 ų (Calculated from Unit Cell)
Z:
16
Morphology:
Rhomboidal scales forming coatings.
Twinning:
Lamellar twinning visible when plates turned on edge. Small extinction angles.
Comment:
Point Group: 2/m or 2

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
12.6 Å(100)
8.70 Å(100)
9.65 Å(80)
7.10 Å(60)
4.32 Å(50)
6.13 Å(40)
4.65 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):

Type Occurrence of VogliteHide

General Appearance of Type Material:
Aggregates of bundled scales.
Place of Conservation of Type Material:
No designated type material.
Geological Setting of Type Material:
Uranium deposit. Oxidation product of uraninite.
Associated Minerals at Type Locality:

Other Language Names for VogliteHide

Common AssociatesHide

Associations Based on Photo Data:
18 photos of Voglite associated with ZelleriteCa(UO2)(CO3)2 · 5H2O
16 photos of Voglite associated with LiebigiteCa2(UO2)(CO3)3 · 11H2O
6 photos of Voglite associated with GypsumCaSO4 · 2H2O
5 photos of Voglite associated with UraniniteUO2
2 photos of Voglite associated with 'Sandstone'
2 photos of Voglite associated with GoethiteFe3+O(OH)
2 photos of Voglite associated with MetazelleriteCa(UO2)(CO3)2 · 3H2O
1 photo of Voglite associated with 'Limonite'
1 photo of Voglite associated with ChalcociteCu2S
1 photo of Voglite associated with AzuriteCu3(CO3)2(OH)2

Related Minerals - Strunz-mindat GroupingHide

5.EE.10Shabaite-(Nd)Nd2Ca[(UO2)(CO3)3](CO3)2(H2O)10.5Tric. 1 : P1

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 31.2433% 7,810,825 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 0.0000% 0 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

Notes:
Soluble in acids with effervescence.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for VogliteHide

References for VogliteHide

Reference List:

Localities for VogliteHide

Showing 12 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Czech Republic (TL)
 
  • Karlovy Vary Region
    • Karlovy Vary District
      • Jáchymov
Palache et al. (1951) +1 other reference
  • Vysočina Region
    • Žďár nad Sázavou District
      • Nové Město na Moravě
Pauliš P. et al. (Kutna Hora, issue 1) +1 other reference
France
 
  • Brittany
    • Côtes-d'Armor
      • Saint-Brieuc
        • Le Mené
- (1998)
- (1998)
Germany
 
  • Saxony
    • Erzgebirgskreis
      • Annaberg-Buchholz
        • Kleinrückerswalde
In the collection of Brent Thorne. ...
      • Breitenbrunn
...
Poland
 
  • Lower Silesian Voivodeship
    • Zgorzelec County
      • Bogatynia
        • Markocice
Banaś M.
USA
 
  • Arizona
    • Navajo County
      • Red Mesa District
Galbraith (1959) +1 other reference
  • Montana
    • Jefferson County
      • Clancy-Lump Gulch Mining District
Meschter (1953)
A Listing of North Carolina Minerals- ...
...
  • Utah
    • San Juan County
      • White Canyon Mining District
        • Fry Mesa
Bullock (1981)
 
and/or  
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