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Middendorfite

A valid IMA mineral species
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About MiddendorfiteHide

00274390017272471082225.jpg
Alexander Theodor von Middendorff
Formula:
K3Na2Mn5Si12(O,OH)36 · 2H2O
Colour:
Dark to bright orange
Lustre:
Vitreous
Hardness:
3 - 3½
Specific Gravity:
2.60
Crystal System:
Monoclinic
Name:
For Aleksandr Fedorovich von Middendorf (18 August 1815 – 24 January 1894), a German-Russian scientist who made the first mineralogical studies on the Khibiny massif.

Unique IdentifiersHide

Mindat ID:
28996
Long-form identifier:
mindat:1:1:28996:8

IMA Classification of MiddendorfiteHide

Classification of MiddendorfiteHide

9.EJ.10

9 : SILICATES (Germanates)
E : Phyllosilicates
J : Unclassified phyllosilicates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MddIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MiddendorfiteHide

Vitreous
Transparency:
Transparent
Colour:
Dark to bright orange
Streak:
Yellowish
Hardness:
3 - 3½ on Mohs scale
Tenacity:
Flexible
Cleavage:
Perfect
on (001)
Fracture:
Sub-Conchoidal
Comment:
fracture scaly
Density:
2.60 g/cm3 (Measured)    2.65 g/cm3 (Calculated)

Optical Data of MiddendorfiteHide

Type:
Biaxial (-)
RI values:
nα = 1.534(3) nβ = 1.562(2) nγ = 1.563(2)
2V:
Measured: 10° (5), Calculated: 21°
Max. Birefringence:
δ = 0.029
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Pleochroism:
Strong
Comments:
X = yellowish to colorless; Y = brown;
Z = deep brown

Chemistry of MiddendorfiteHide

Mindat Formula:
K3Na2Mn5Si12(O,OH)36 · 2H2O
Element Weights:
Element% weight
O43.834 %
Si24.299 %
Mn19.805 %
K8.457 %
Na3.315 %
H0.291 %

Calculated from ideal end-member formula.

Crystallography of MiddendorfiteHide

Crystal System:
Monoclinic
Cell Parameters:
a = 12.55(1) Å, b = 5.721(2) Å, c = 26.86(2) Å
β = 114.04(7)°
Ratio:
a:b:c = 2.194 : 1 : 4.695
Unit Cell V:
1761 ų
Z:
2
Comment:
Point Group: 2/m or 2; Space Group: P21/m or P21.

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of MiddendorfiteHide

General Appearance of Type Material:
Coarse, rhomb-like lamellar and tabular crystals up to 0.1 x 0.2 x 0.4 mm in size, combined in worm- and fan-like aggregates up to 1 mm
Place of Conservation of Type Material:
A.E. Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, 3312/1.
Geological Setting of Type Material:
late hydrothermal mineral in a hyperperalkaline pegmatite
Associated Minerals at Type Locality:

Synonyms of MiddendorfiteHide

Other Language Names for MiddendorfiteHide

Related Minerals - Strunz-mindat GroupingHide

9.EJ.05Lourenswalsite(K,Ba)2(Ti,Mg,Ca,Fe)4(Si,Al,Fe)6O14(OH)12Hex.
9.EJ.15LipuiteKNa8Mn3+5 Mg0.5[Si12O30(OH)4](PO4)O2(OH)2 · 4H2OOrth. mmm(2/m2/m2/m) : Pnnm
9.EJ.20OdigitriaiteCsNa5Ca5[Si14B2O38]F2Mon. 2/m : B2/b

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 8.4567% 2,622 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MiddendorfiteHide

References for MiddendorfiteHide

Localities for MiddendorfiteHide

Showing 1 localities.

ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Murmansk Oblast
    • Kukisvumchorr Mt
      • Kirovskii apatite mine
        • 252 m level
Pekov et al. (2006)
 
and/or  
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