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Paravinogradovite

A valid IMA mineral species

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Paravinogradovite

Northeast slope, Kukisvumchorr Mt, Murmansk Oblast, Russia

Paravinogradovite

Northeast slope, Kukisvumchorr Mt, Murmansk Oblast, Russia

Paravinogradovite

Northeast slope, Kukisvumchorr Mt, Murmansk Oblast, Russia

Paravinogradovite

Northeast slope, Kukisvumchorr Mt, Murmansk Oblast, Russia

Paravinogradovite

Northeast slope, Kukisvumchorr Mt, Murmansk Oblast, Russia

Paravinogradovite

Northeast slope, Kukisvumchorr Mt, Murmansk Oblast, Russia

Paravinogradovite

Northeast slope, Kukisvumchorr Mt, Murmansk Oblast, Russia

Paravinogradovite

Northeast slope, Kukisvumchorr Mt, Murmansk Oblast, Russia

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About ParavinogradoviteHide

Formula:

Na_1-2(Ti,Fe³⁺)₄(Si₂O₆)₂(AlSi₃O₁₀)(OH)₄ · H₂O

Colour:

Colourless to white

Lustre:

Vitreous, Pearly

Hardness:

Specific Gravity:

2.77

Crystal System:

Triclinic

Name:

For its structural relation to vinogradovite. First described by Khomyakov (1990,1995) as a potential new species, designated as M48, a vinogradovite-like mineral. It was first collected by him in 1986 and by Pavel M. Kartashov in 1988 from the central part of the Khibina alkaline massif, Kola, Russia. Described as a new mineral by Khomyakov et al. (2003).

Type Locality:

ⓘ Northeast slope, Kukisvumchorr Mt, Murmansk Oblast, Russia

A secondary mineral formed from vinogradovite (Khomyakov et al. 2003).

Unique IdentifiersHide

Mindat ID:

25599

Long-form identifier:

mindat:1:1:25599:8

IMA Classification of ParavinogradoviteHide

IMA status:

Approved

IMA Formula:

(Na,◻)₂(Ti⁴⁺,Fe³⁺)₄(Si₂O₆)₂(Si₃AlO₁₀)(OH)₄·H₂O

Approval year:

2002

First published:

1990

Type description reference:

Khomyakov, A. P., Kulikova, I. E., Sokolova, E., Hawthorne, F. C., Kartashov, P. M. (2003) Paravinogradovite, (Na,◻)₂[(Ti⁴⁺,Fe³⁺)₄{Si₂O₆}₂{Si₃AlO₁₀}(OH)₄]H₂O, a new mineral species from the Khibina Alkaline Massif, Kola Peninsula, Russia: description and crystal structure. The Canadian Mineralogist, 41 (4) 989-1002 doi:10.2113/gscanmin.41.4.989

Classification of ParavinogradoviteHide

Strunz-mindat (2026):

9.DB.25

9 : SILICATES (Germanates)
D : Inosilicates
B : Inosilicates with 2-periodic single chains, Si₂O₆; Pyroxene-related minerals

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference for Standard
Pvgd	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ParavinogradoviteHide

Lustre:

Vitreous, Pearly

Colour:

Colourless to white

Streak:

White

Hardness:

5 on Mohs scale

Tenacity:

Brittle

Cleavage:

Perfect
Perfect on {001} and indistinct {010}

Fracture:

Splintery

Density:

2.77(2) g/cm³ (Measured) 2.76 g/cm³ (Calculated)

Optical Data of ParavinogradoviteHide

Type:

Biaxial (-)

RI values:

n_α = 1.707(2) n_β = 1.741(2) n_γ = 1.755(2)

2V:

Measured: 64° (1), Calculated: 64°

Max. Birefringence:

δ = 0.048
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Thickness: 30 µm Order divisions

Rotation:

Surface Relief:

Moderate

Dispersion:

r > v

Optical Extinction:

b ≈ Z, a ∧ X = 30°

Pleochroism:

Non-pleochroic

Comments:

Negative elongation

Chemistry of ParavinogradoviteHide

Mindat Formula:

Na_1-2(Ti,Fe³⁺)₄(Si₂O₆)₂(AlSi₃O₁₀)(OH)₄ · H₂O

Element Weights:

Element	% weight
O	49.309 %
Si	22.441 %
Ti	21.855 %
Al	3.080 %
Na	2.624 %
H	0.690 %

Calculated from ideal end-member formula.

Elements listed:

Al, Fe, H, Na, O, Si, Ti - search for minerals with similar chemistry

Crystallography of ParavinogradoviteHide

Crystal System:

Triclinic

Class (H-M):

1 - Pedial

Space Group:

Cell Parameters:

a = 5.253 Å, b = 8.741 Å, c = 12.95 Å
α = 70.46°, β = 78.47°, γ = 89.93°

Ratio:

a:b:c = 0.601 : 1 : 1.482

Unit Cell V:

547.68 Å³ (Calculated from Unit Cell)

Morphology:

Slender to acicular prismatic crystals.

Crystal StructureHide

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Unit Cell | Unit Cell Packed
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CIF File Best | x | y | z | a | b | c

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0005880	Paravinogradovite	Khomyakov A P, Kulikova I E, Sokolova E V, Hawthorne F C, Kartashov P M (2003) Paravinogradovite, (Na,_)2[(Ti,Fe)4{Si2O6}2{Si3AlO10}(OH)4]H2O, a new mineral species from the Khibina Alkaline Massif, Kola Penninsula, Russia: Description and crystal structure The Canadian Mineralogist 41 989-1002		2003	Khibina Alkaline Massif, Kola Penninsula, Russia	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Paravinogradovite'
loop_
_publ_author_name
'Khomyakov A P'
'Kulikova I E'
'Sokolova E V'
'Hawthorne F C'
'Kartashov P M'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 41 
_journal_year 2003
_journal_page_first 989
_journal_page_last 1002
_publ_section_title
;
 Paravinogradovite, (Na,_)2[(Ti,Fe)4{Si2O6}2{Si3AlO10}(OH)4]H2O, a new mineral species
 from the Khibina Alkaline Massif, Kola Penninsula, Russia: Description and crystal structure
;
_database_code_amcsd 0005880
_chemical_compound_source 'Khibina Alkaline Massif, Kola Penninsula, Russia'
_chemical_formula_sum 'Na2.07 K.13 (Ti3.52 Fe.48) Si7.6 Al.1 Be.3 O27.17 H6.34'
_cell_length_a 5.2533
_cell_length_b 8.7411
_cell_length_c 12.9480
_cell_angle_alpha 70.466
_cell_angle_beta 78.472
_cell_angle_gamma 89.932
_cell_volume 547.654
_exptl_crystal_density_diffrn      2.753
_symmetry_space_group_name_H-M 'P 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
NaX(1)  -0.00440   0.45330   0.20920   0.76000   0.02130
NaX(2)  -0.51250  -0.15990   0.20990   0.43000   0.01800
NaX(3)  -0.52200   0.15400  -0.20200   0.16000   0.04800
NaA(1)  -0.14400  -0.00700  -0.50690   0.18000   0.05000
NaA(2)  -0.33800  -0.00900  -0.49490   0.20000   0.05000
NaA(3)   0.25000  -0.00700  -0.50400   0.15000   0.05000
NaA(4)   0.40300  -0.06900  -0.50530   0.19000   0.05000
KA(5)  -0.16700   0.11900  -0.50180   0.13000   0.05000
TiM(1)  -0.00260   0.04863   0.19107   0.88000   0.01010
FeM(1)  -0.00260   0.04863   0.19107   0.12000   0.01010
TiM(2)  -0.01290  -0.04434  -0.19148   0.88000   0.00900
FeM(2)  -0.01290  -0.04434  -0.19148   0.12000   0.00900
TiM(3)  -0.49460   0.26018   0.19098   0.88000   0.01090
FeM(3)  -0.49460   0.26018   0.19098   0.12000   0.01090
TiM(4)   0.48620  -0.26523  -0.18922   0.88000   0.00860
FeM(4)   0.48620  -0.26523  -0.18922   0.12000   0.00860
SiT(1)   0.29150   0.35660  -0.03811   0.90000   0.00770
AlT(1)   0.29150   0.35660  -0.03811   0.10000   0.00770
SiT(2)  -0.30670  -0.35110   0.03801   1.00000   0.00820
SiT(3)  -0.20820   0.18830  -0.04019   1.00000   0.00790
SiT(4)   0.19500  -0.17670   0.03601   0.70000   0.00680
BeT(4)   0.19500  -0.17670   0.03601   0.30000   0.00680
SiT(5)   0.20620   0.33360  -0.36896   1.00000   0.01090
SiT(6)  -0.64350   0.46110   0.37055   1.00000   0.01090
SiT(7)   0.70220  -0.46720  -0.36715   1.00000   0.01160
SiT(8)  -0.14730  -0.33840   0.37178   1.00000   0.00810
O(1)   0.22980   0.27590   0.10010   1.00000   0.00890
O(2)  -0.27270   0.12800   0.09820   1.00000   0.00920
O(3)   0.18200  -0.02660   0.07960   1.00000   0.01250
O(4)  -0.31900   0.45080   0.08740   1.00000   0.01270
O-h(5)  -0.22300   0.18450   0.27030   1.00000   0.00900
O-h(6)   0.28060   0.04620   0.26960   1.00000   0.01020
O(7)   0.06220   0.29840  -0.08800   1.00000   0.01170
O(8)   0.56330   0.29260  -0.08730   1.00000   0.01030
O(9)  -0.15980  -0.14030   0.28510   1.00000   0.01380
O(10)  -0.24390  -0.33990   0.50740   1.00000   0.02590
O(11)  -0.66610   0.34830   0.29220   1.00000   0.01530
O(12)  -0.83840   0.60440   0.34550   1.00000   0.01820
O(13)  -0.34980   0.53200   0.34360   1.00000   0.01990
O-h(14)   0.21230  -0.18330  -0.27100   1.00000   0.01440
O-h(15)  -0.28480  -0.05420  -0.27270   1.00000   0.01410
O(16)   0.25600  -0.13110  -0.09870   1.00000   0.01000
O(17)  -0.24600  -0.27070  -0.09750   1.00000   0.01020
O(18)  -0.18550   0.03230  -0.08370   1.00000   0.01160
O(19)  -0.08200  -0.29100   0.08750   1.00000   0.01030
O(20)   0.31020   0.55130  -0.07780   1.00000   0.01070
O(21)  -0.58390  -0.29290   0.08800   1.00000   0.01280
O(22)   0.15280   0.14190  -0.29230   1.00000   0.01750
O(23)   0.26980   0.34090  -0.49900   1.00000   0.01880
O(24)   0.65090  -0.36430  -0.28390   1.00000   0.01970
O(25)   0.95770  -0.56870  -0.34440   1.00000   0.03590
O(26)   0.45520   0.40750  -0.34310   1.00000   0.03120
Wat(27)   0.26000  -0.16200  -0.50030   0.48000   0.05000
Wat(28)  -0.31600   0.12000  -0.49360   0.38000   0.05000
Wat(29)   0.09200  -0.06500  -0.49220   0.31000   0.05000
H(1)  -0.23900   0.15100   0.34840   1.00000   0.01080
H(2)   0.27600  -0.04200   0.34500   1.00000   0.01200
H(3)   0.11800  -0.24300  -0.30900   1.00000   0.01700
H(4)  -0.36000   0.02900  -0.29800   1.00000   0.01700
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
NaX(1) 0.02200 0.01700 0.02700 0.00330 -0.01200 -0.00750
NaX(2) 0.01400 0.02600 0.01700 0.00700 -0.00900 -0.00800
NaX(3) 0.05400 0.02500 0.09000 0.00100 -0.05100 -0.03100
TiM(1) 0.01260 0.00870 0.00820 0.00200 -0.00240 -0.00170
FeM(1) 0.01260 0.00870 0.00820 0.00200 -0.00240 -0.00170
TiM(2) 0.00900 0.00830 0.00890 0.00030 -0.00040 -0.00270
FeM(2) 0.00900 0.00830 0.00890 0.00030 -0.00040 -0.00270
TiM(3) 0.01290 0.00940 0.01060 -0.00110 0.00030 -0.00530
FeM(3) 0.01290 0.00940 0.01060 -0.00110 0.00030 -0.00530
TiM(4) 0.00800 0.01040 0.00770 -0.00050 -0.00020 -0.00420
FeM(4) 0.00800 0.01040 0.00770 -0.00050 -0.00020 -0.00420
SiT(1) 0.00750 0.00780 0.00810 0.00070 -0.00070 -0.00370
AlT(1) 0.00750 0.00780 0.00810 0.00070 -0.00070 -0.00370
SiT(2) 0.00700 0.00750 0.00900 0.00060 -0.00270 -0.00080
SiT(3) 0.00660 0.01090 0.00650 0.00200 -0.00100 -0.00350
SiT(4) 0.00490 0.00640 0.00920 -0.00080 -0.00100 -0.00290
BeT(4) 0.00490 0.00640 0.00920 -0.00080 -0.00100 -0.00290
SiT(5) 0.01230 0.01070 0.00740 -0.00020 -0.00090 -0.00050
SiT(6) 0.00990 0.01340 0.00880 0.00040 -0.00120 -0.00340
SiT(7) 0.01510 0.01130 0.00820 -0.00150 0.00060 -0.00460
SiT(8) 0.00820 0.00680 0.00850 -0.00010 -0.00020 -0.00230
O(1) 0.00900 0.00600 0.01000 0.00030 -0.00230 -0.00100
O(2) 0.01000 0.00900 0.00800 -0.00130 -0.00150 -0.00200
O(3) 0.01300 0.01400 0.01500 0.00260 -0.00400 -0.01000
O(4) 0.01200 0.01100 0.01100 -0.00350 -0.00320 0.00200
O-h(5) 0.01000 0.00900 0.00700 -0.00200 0.00090 -0.00200
O-h(6) 0.01300 0.01000 0.00600 -0.00190 -0.00280 -0.00100
O(7) 0.00700 0.01700 0.01200 -0.00740 -0.00180 -0.00700
O(8) 0.00800 0.01100 0.01100 0.00240 -0.00210 -0.00400
O(9) 0.02000 0.01100 0.00700 -0.00300 -0.00300 0.00200
O(10) 0.04700 0.01400 0.01400 0.00300 -0.00400 -0.00300
O(11) 0.01600 0.01800 0.01700 0.00350 -0.00400 -0.01000
O(12) 0.01700 0.01900 0.01800 0.00180 0.00090 -0.00920
O(13) 0.01600 0.01900 0.02400 -0.00190 -0.00230 -0.00700
O-h(14) 0.01100 0.02100 0.01400 0.01000 -0.00700 -0.00800
O-h(15) 0.01100 0.01400 0.01600 -0.00050 -0.00100 -0.00500
O(16) 0.00700 0.01400 0.00800 -0.00130 0.00020 -0.00500
O(17) 0.01100 0.01500 0.00400 -0.00110 -0.00280 0.00000
O(18) 0.00900 0.01000 0.01700 0.00200 -0.00150 -0.00700
O(19) 0.00600 0.01500 0.00700 -0.00170 -0.00020 -0.00100
O(20) 0.01100 0.00700 0.01400 0.00390 -0.00240 -0.00300
O(21) 0.01000 0.01800 0.00600 0.00440 -0.00110 0.00200
O(22) 0.01500 0.01400 0.01700 -0.00800 0.00400 -0.00200
O(23) 0.02700 0.02000 0.00600 -0.00100 0.00300 -0.00300
O(24) 0.02500 0.02300 0.01500 0.00800 -0.00300 -0.01200
O(25) 0.03400 0.04200 0.02700 0.01800 0.00100 -0.00900
O(26) 0.04100 0.02700 0.02000 -0.01900 -0.00800 -0.00100

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
11.9 Å	(60)
5.88 Å	(65)
3.18 Å	(100)

Locality:

Northeast slope, Kukisvumchorr Mt, Murmansk Oblast, Russia

Reference:

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 4b: Highly evolved igneous rocks	>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of ParavinogradoviteHide

Type Locality:

ⓘ Northeast slope, Kukisvumchorr Mt, Murmansk Oblast, Russia

General Appearance of Type Material:

Fan-shaped aggregates of slender to acicular prismatic crystals to 10 mm, pseudomorphing vinogradovite.

Place of Conservation of Type Material:

A.E. Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, Russia (2883/1).

Geological Setting of Type Material:

In vugs of an albite rich pegmatite lens.

Associated Minerals at Type Locality:

Aegirine	Anatase	'Carbonate-rich Fluorapatite'	Cerussite	Fluorite
Galena	'Glauconite'	Natrolite	Nordstrandite

Reference:

Synonyms of ParavinogradoviteHide

IMA2002-033

Паравиноградовит

Other Language Names for ParavinogradoviteHide

Dutch:Paravinogradoviet

German:Paravinogradovit

Russian:Паравиноградовит

Simplified Chinese:副白钛硅钠石

Traditional Chinese:副白鈦矽鈉石

Common AssociatesHide

Associations Based on Photo Data:

1 photo of Paravinogradovite associated with Microcline

K(AlSi₃O₈)

Related Minerals - Strunz-mindat Grouping Hide

9.DB.05	Potassiccarpholite	K(Mn²⁺,Li)₂Al₄Si₄O₁₂(OH,F)₈	Orth. mmm(2/m2/m2/m) : Ccca
9.DB.05	Carpholite	Mn²⁺Al₂(Si₂O₆)(OH)₄	Orth. mmm(2/m2/m2/m) : Ccca
9.DB.05	Vanadiocarpholite	Mn²⁺V³⁺Al(Si₂O₆)(OH)₄	Orth. mmm(2/m2/m2/m) : Ccca
9.DB.05	Magnesiocarpholite	MgAl₂Si₂O₆(OH)₄	Orth. mmm(2/m2/m2/m) : Ccca
9.DB.05	Ferrocarpholite	Fe²⁺Al₂Si₂O₆(OH)₄	Orth. mmm(2/m2/m2/m) : Ccca
9.DB.05	Balipholite	BaLiMg₂Al₃(Si₂O₆)₂(OH)₄	Orth. mmm(2/m2/m2/m) : Ccca
9.DB.10	Lorenzenite	Na₂Ti₂(Si₂O₆)O₃	Orth. mmm(2/m2/m2/m) : Pbcn
9.DB.15	Punkaruaivite	LiTi₂(HSi₄O₁₂)(OH)₂ · H₂O	Mon. 2/m : B2/b
9.DB.15	Lintisite	LiNa₃Ti₂(Si₂O₆)₂O₂ · 2H₂O	Mon. 2/m : B2/b
9.DB.17	Eliseevite	LiNa_1.5Ti₂(H_1.5Si₄O₁₂)O₂ · 2H₂O	Mon. 2/m : B2/b
9.DB.20	Kukisvumite	Na₆ZnTi₄(Si₈O₂₄)O₄ · 4H₂O	Orth. mmm(2/m2/m2/m) : Pccn
9.DB.20	Manganokukisvumite	Na₆MnTi₄(Si₈O₂₄)O₄ · 4H₂O	Orth. mmm(2/m2/m2/m) : Pccn
9.DB.25	Vinogradovite	Na₄Ti₄(Si₂O₆)₂[(Si,Al)₄O₁₀]O₄ · (H₂O,Na,K)₃	Mon. 2/m : B2/b
9.DB.30	Nchwaningite	Mn²⁺₂(SiO₃)(OH)₂ · H₂O	Orth. mm2 : Pca2₁
9.DB.40	Shattuckite	Cu₅(Si₂O₆)₂(OH)₂	Orth. mmm(2/m2/m2/m)
9.DB.40	'UM2005-31-SiO:CuH'	Cu₁₁(SiO₄)(OH)₁₈ · 9H₂O (?)
9.DB.45	Aerinite	(Ca_5.1Na_0.5)(Fe³⁺,Al,Fe²⁺,Mg)₄(Al,Mg)₆[HSi₁₂O₃₆(OH)₁₂][(CO₃)_1.2(H₂O)₁₂]	Trig. 3m : P3c1
9.DB.50	Capranicaite	KCaNaAl₄B₄Si₂O₁₈	Mon. 2/m : P2₁/m

Fluorescence of ParavinogradoviteHide

In UV light:

Weak yellow-green fluorescence in short-wave UV light.

Other InformationHide

Notes:

Not reactive in 1:1 HCl and HNO3 at room or higher temperature.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ParavinogradoviteHide

mindat.org URL:

https://www.mindat.org/min-25599.html
Please feel free to link to this page.

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References for ParavinogradoviteHide

Reference List:

Khomyakov, A. P. (1990) Mineralogy of Hyperagpaitic Alkaline rocks. Nauka, Moscow, Russia (in Russian)[as a vinogradovite-like mineral]

Khomyakov, A. P. (1995) Mineralogy of Hyperagpaitic Alkaline Rocks. Clarendon Press. 223 pp.[as a vinogradovite-like mineral]

Jambor, J.L., Roberts, A.C. (2004) New Mineral Names. American Mineralogist, 89, 894–897.

(2021) Paravinogradovite. Handbook of Mineralogy. Mineralogical Society of America

Localities for ParavinogradoviteHide

Showing 1 localities.

ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Russia (TL)

Murmansk Oblast

Kukisvumchorr Mt

ⓘ Northeast slope (TL)

Khomyakov et al. (2003) +1 other reference

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Paravinogradovite

About ParavinogradoviteHide

Unique IdentifiersHide

IMA Classification of ParavinogradoviteHide

Classification of ParavinogradoviteHide

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Physical Properties of ParavinogradoviteHide

Optical Data of ParavinogradoviteHide

Chemistry of ParavinogradoviteHide

Crystallography of ParavinogradoviteHide

Crystal StructureHide

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Type Occurrence of ParavinogradoviteHide

Synonyms of ParavinogradoviteHide

Other Language Names for ParavinogradoviteHide

Common AssociatesHide

Related Minerals - Strunz-mindat GroupingHide

Fluorescence of ParavinogradoviteHide

Other InformationHide

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Localities for ParavinogradoviteHide

Related Minerals - Strunz-mindat Grouping Hide