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Hellyerite

A valid IMA mineral species
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About HellyeriteHide

01124600017271923791397.jpg
Gravestone of Henry Hellyer
Formula:
NiCO3 · 5.5H2O
Colour:
Pale blue
Lustre:
Vitreous
Hardness:
Specific Gravity:
1.97
Crystal System:
Monoclinic
Name:
In honour of Henry Hellyer (1791– September 2, 1832), first Surveyor-General of the Van Diemen’s Land Company and explorer of northwestern Tasmania.
Hellyerite is relatively unstable and, if not kept in an air-tight environment, the (originally) blue mineral decomposes in time to an X-ray amorphous, zaratite-like green phase, and other secondary nickel minerals (Anderson et al., 2002; Bottrill & Baker, 2008).


Unique IdentifiersHide

Mindat ID:
1853
Long-form identifier:
mindat:1:1:1853:7

Similar NamesHide

HilairiteA valid IMA mineral speciesNa2Zr[SiO3]3 · 3H2O

IMA Classification of HellyeriteHide

Approved
IMA Formula:
Ni2+CO3·6H2O
First published:
1959

Classification of HellyeriteHide

5.CA.20

5 : CARBONATES (NITRATES)
C : Carbonates without additional anions, with H2O
A : With medium-sized cations
15.1.7.1

15 : HYDRATED NORMAL CARBONATES
1 : A(XO3)·xH2O
11.14.4

11 : Carbonates
14 : Carbonates of Co and Ni

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
HyIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HellyeriteHide

Vitreous
Transparency:
Transparent
Colour:
Pale blue
Hardness:
2½ on Mohs scale
Cleavage:
Perfect
One perfect and 2 good cleavages
Density:
1.97 g/cm3 (Measured)    1.98 g/cm3 (Calculated)

Optical Data of HellyeriteHide

Type:
Biaxial (-)
RI values:
nα = 1.455(2) nβ = 1.503(2) nγ = 1.549(2)
2V:
Measured: 85° , Calculated: 86°
Max. Birefringence:
δ = 0.094
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Dispersion:
r > v distinct
Pleochroism:
Weak
Comments:
X = very pale greenish blue, Y = very pale greenish blue and Z = pale greenish blue.

Chemistry of HellyeriteHide

Mindat Formula:
NiCO3 · 5.5H2O
Element Weights:
Element% weight
O62.444 %
Ni26.950 %
C5.515 %
H5.091 %

Calculated from ideal end-member formula.

Crystallography of HellyeriteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P2/m
Setting:
P2/m
Cell Parameters:
a = 10.769(2) Å, b = 7.295(2) Å, c = 9.343(2) Å
β = 94°
Ratio:
a:b:c = 1.476 : 1 : 1.281
Unit Cell V:
732.20 ų (Calculated from Unit Cell)
Z:
4
Twinning:
lamellar twinning occurs parallel to the perfect cleavage, individual twin lamellae ranging from 0.002 mm. to 0.03 mm. in width.
Comment:
synthetic

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.4 Å(100)
6.06 Å(100)
3.65 Å(70)
3.40 Å(60)
2.38 Å(50)
3.11 Å(40)
2.78 Å(40)
Comments:
Lord Brassey mine, Tasmania, Australia. Data from type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47c : [Carbonates, phosphates, borates, nitrates]

Type Occurrence of HellyeriteHide

General Appearance of Type Material:
Extremely fine-grained coatings up to 1.0 mm. thick.
Place of Conservation of Type Material:
Harvard University, Cambridge, Massachusetts, USA, 108400.
Geological Setting of Type Material:
Oxidation of nickel sulfides.
Associated Minerals at Type Locality:

Other Language Names for HellyeriteHide

German:Hellyerit
Spanish:Hellyerita

Common AssociatesHide

Associations Based on Photo Data:
10 photos of Hellyerite associated with ZaratiteNi3(CO3)(OH)4 · 4H2O ?
6 photos of Hellyerite associated with HeazlewooditeNi3S2
3 photos of Hellyerite associated with ReevesiteNi6Fe3+2(OH)16(CO3) · 4H2O
2 photos of Hellyerite associated with MagnetiteFe2+Fe3+2O4
2 photos of Hellyerite associated with Serpentine SubgroupD3[Si2O5](OH)4
1 photo of Hellyerite associated with Pentlandite(NixFey)Σ9S8

Related Minerals - Strunz-mindat GroupingHide

5.CA.05NesquehoniteMgCO3 · 3H2OMon. 2/m : P21/m
5.CA.10LansforditeMgCO3 · 5H2OMon. 2/m : P21/b
5.CA.15'Barringtonite'MgCO3 · 2H2OTric.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HellyeriteHide

References for HellyeriteHide

Localities for HellyeriteHide

Showing 4 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia (TL)
 
  • Tasmania
    • Waratah-Wynyard municipality
      • Heazlewood district
Williams et al. (1959) +1 other reference
Poland
 
  • Greater Poland Voivodeship
    • Poznań
Karwowski et al. (2011) +1 other reference
South Africa
 
  • Limpopo
    • Vhembe District Municipality
      • Musina Local Municipality
Cairncross et al. (1995)
Cairncross et al. (1995)
 
and/or  
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